Characterization of high- and low-molecular-weight

phase1tox

Characterization of high- and low-molecular-weight glutenin subunits from Chinese language Xinjiang wheat landraces and historic varieties

 Landraces and historic varieties are obligatory germplasms for genetic enchancment of recent cereals. Allelic variations on the <i>Glu</i>-<i>1</i> and <i>Glu</i>-<i>3</i> loci in 300 widespread wheat landraces and 43 historic varieties from Xinjiang, China, have been evaluated by Sodium-dodecyl-sulfate polyacrylamide gel electrophoresis (SDS-PAGE) and allele-specific molecular markers. Among the many supplies investigated, three, 9, and 7 alleles have been recognized from the <i>Glu</i>-<i>A1</i>, <i>Glu</i>-<i>B1</i>, and <i>Glu</i>-<i>D1</i> loci, respectively, and a complete of 26 high-molecular-weight glutenin subunit (HMW-GS) mixtures have been discovered, of which 18 mixtures have been recognized in landraces and historic varieties.

Allelic frequency of HMW-GS mixtures null, 7 + 8, 2 + 12 was discovered to be the best in each the landraces (63.3%) and historic varieties (39.5%). Moreover, some distinctive HMW-GS alleles, such because the novel <i>Glu</i>-<i>B1</i> allele 6.1* + 8.1* and <i>Glu</i>-<i>D1</i> alleles 2.6 + 12, 2.1 + 10.1, and 5** + 10 have been noticed in Xinjiang wheat landraces. Among the many <i>Glu</i>-<i>A3</i> and <i>Glu</i>-<i>B3</i> loci of landraces and historic varieties, a complete of eight and 9 alleles have been discovered, respectively.

At every locus, two novel alleles have been recognized. A complete of 33 low-molecular-weight glutenin subunit (LMW-GS) mixtures of <i>Glu</i>-<i>A3</i> and <i>Glu</i>-<i>B3</i> have been recognized, with 31 and 14 mixtures occurring in landraces and historic varieties, respectively, however solely 10 mixtures shared by each of them. As <i>Glu</i>-<i>D1</i>, <i>Glu</i>-<i>A3</i>, and <i>Glu</i>-<i>B3</i> have highest contribution to the end-use high quality and processing properties as in contrast to <i>Glu</i>-<i>A1</i>, <i>Glu</i>-<i>B1</i>, and <i>Glu</i>-<i>D3</i> locus, the novel or distinctive HMW-GS and LMW-GS alleles in these loci might probably be utilized for the development within the high quality of recent wheat.

phase1tox
phase1tox

Agarose B, Low EEO

AB0014 50g
EUR 99.67

Agarose LE Low EEO

AXY1000 PK10
EUR 2058.84

Agarose LE Low EEO

AXY1002 PK10
EUR 8391.54

AGAROSE LE, LOW EEO, MOLECULAR BIOLOGY GRADE, 100G PER UNIT

AGR-LE-100 1/pk
EUR 201.6
Description: Bioscience Mol Bio; Agarose

Agarose, medium EEO

GE4750-100G 100 g
EUR 199.2

Agarose, medium EEO

GE4750-500G 500 g
EUR 514.8

Agarose, low EEO, GlenBiol, suitable for molecular biology

GE6258-100G 100 g
EUR 217.2

AGAROSE LE, LOW EEO, MOLECULAR BIOLOGY GRADE, 500G/UNIT, 10 UNITS PER CASE

AGR-LE-5001 1/pk
EUR 3669.6
Description: Bioscience Mol Bio; Agarose

AGAROSE LE, LOW EEO, MOLECULAR BIOLOGY GRADE, 100G PER UNIT, 10 UNITS PER CASE

AGR-LE-1001 1/pk
EUR 926.4
Description: Bioscience Mol Bio; Agarose

Agarose, Molecular Grade

BIO-41025 500g Ask for price

Agarose, Molecular Grade

BIO-41026 100g Ask for price

HiQTM Low Melting Agarose

A0223-002 25g
EUR 343.2

HiQTM Low Melting Agarose

A0223-010 100g
EUR 699.6

Agarose, Low melting gel

AB0015 10g
EUR 96.54

Agarose LM Low Melting

AXY1004 PK10
EUR 10277.1

Agarose LM Low Melting

AXY1006 PK10
EUR 5669.22

Agarose GPG/LMP low melt

A2501-100000 100 g
EUR 510
Description: Agarose has a wide range of physical, chemical and thermal stability, because of its greatest gelling ability that it acquires wide applications in biotechnology [2], such as agarose gel electrophoresis, protein purification, solid culture media, motility assays.

Agarose GPG/LMP low melt

A2501-25000 25 g
EUR 184.8
Description: Agarose has a wide range of physical, chemical and thermal stability, because of its greatest gelling ability that it acquires wide applications in biotechnology [2], such as agarose gel electrophoresis, protein purification, solid culture media, motility assays.

Agarose II, Low Gelling Temperature

CH002 25 g
EUR 274.8

Agarose II, Low Gelling Temperature

CH003 100 g
EUR 525.6

HyAgarose? HR Agarose, PCR Grade, 100g

R9012HR-100g
EUR 398.4

HyAgarose? HR Agarose, PCR Grade, 10g

R9012HR-10g
EUR 99.6

HyAgarose? HR Agarose, PCR Grade, 500g

R9012HR-500g
EUR 1369.2

HyAgarose? HR Agarose, PCR Grade, 50g

R9012HR-50g
EUR 242.4

HyAgarose? LM Agarose, Low Melting, 100g

R9012LM-100g
EUR 452.4

HyAgarose? LM Agarose, Low Melting, 10g

R9012LM-10g
EUR 120

HyAgarose? LM Agarose, Low Melting, 500g

R9012LM-500g
EUR 1821.6

HyAgarose? LM Agarose, Low Melting, 50g

R9012LM-50g
EUR 262.8

AGAROSE LM, LOW MELTING, MOLECULAR BIOLOGY GRADE, 100G/UNIT, 10 UNITS PER CASE (AL)

AGR-LM-1001 1/pk
EUR 4484.4
Description: Bioscience Mol Bio; Agarose

AGAROSE LM, LOW MELTING, MOLECULAR BIOLOGY GRADE, 50G/UNIT, 10 UNITS PER CASE (AL)

AGR-LM-501 1/pk
EUR 2490
Description: Bioscience Mol Bio; Agarose

Drierite regular

DC3617 500g
EUR 88.84

Agarose LE, Ultra-Pure Molecular Biology Grade, 100 g

41028-100G 100G
EUR 266.4
Description: Minimum order quantity: 1 unit of 100G

Agarose LE, Ultra-Pure Molecular Biology Grade, 25 g

41028-25G 25G
EUR 130.8
Description: Minimum order quantity: 1 unit of 25G

Agarose LE, Ultra-Pure Molecular Biology Grade, 500 g

41028-500G 500G
EUR 862.8
Description: Minimum order quantity: 1 unit of 500G

WHATMAN GRADE 54 HARDENED LOW ASH QUANTI

WHA1454320 EACH
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Regular Unleaded Gasoline

S-RG-1000 1ML
EUR 27.36

Agarose

abx082006-100g 100 g
EUR 292.8

Agarose

abx082007-100g 100 g
EUR 309.6

Agarose

abx082008-100g 100 g
EUR 276

Agarose

20-abx098147
  • EUR 260.40
  • EUR 126.00
  • 100 g
  • 1 g

Agarose

20-abx186369
  • EUR 610.80
  • EUR 360.00
  • 100 g
  • 25 g

Agarose

G060-1 100 g
EUR 211.2

Agarose

G060-2 500 g
EUR 442.8

Agarose

Z5050007 500 g
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Description: None pays much attention to the agarose until your gel comes out all with waves and uneven thickness. Or even worse, the gel comes out all good only to start melting while you are running the electrophoresis wasting you precious samples. Save yourself some trouble and get our agarose which will provide you with excellent gel quality every time.

Agarose

Z5050013 100 g
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Description: None pays much attention to the agarose until your gel comes out all with waves and uneven thickness. Or even worse, the gel comes out all good only to start melting while you are running the electrophoresis wasting you precious samples. Save yourself some trouble and get our agarose which will provide you with excellent gel quality every time.

Regular Plastic Funnels, 60mm

FN001 1 UNIT
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FN002 1 UNIT
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FN006 1 UNIT
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502CS01 PK100
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Blowgun Replacement Needle Regular

FLY1248 EACH
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GAS-20 1ML
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Agarose, Sepro

A0224-010 100g
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Agarose, Sepro

A0224-020 200g
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Agarose, Sepro

A0224-050 500g
EUR 522

Agarose L.M.P

20-abx082386
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  • 10 g
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Agarose M

AB0013 50g
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Agarose LE

A-1270-100 100 g
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Agarose LE

A-1270-500 500 g
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Agarose HR

A-1280-100 100 g
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Agarose HR

A-1280-500 500 g
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Agarose GA

A-1290-100 100 g
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Agarose GA

A-1290-500 500 g
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A-1300-100 100 g
EUR 230.4

Agarose LM

A-1300-25 25 g
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Agarose Tablets

BA50201 100pcs
EUR 130.8
Description: Ultrapure agarose for separation and further analysis of PCR products.

Agarose A

D0012 50g
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Agarose StandardRoomTemperature

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Flocked Swab Regular in Tube

552C PK100
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Regular Unleaded Gasoline (High Level)

S-RG-20K 1ML
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S-WG-25 1ML
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S-WG-50 1ML
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S-WG-75 1ML
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AGAROSE MS, PCR SCREENING, MOLECULAR BIOLOGY GRADE, 100G/UNIT, 10 UNITS PER CASE

AGR-MS-1001 1/pk
EUR 2445.6
Description: Bioscience Mol Bio; Agarose

Mouse serum albumin antigen grade (MSA) (>97%, low endotoxin, low fatty acid, mouse viruses tested)

ALB14-N-10 10 mg
EUR 489.6

Mouse serum albumin (MSA) antigen grade (>97%, low endotoxin, low fatty acid, mouse viruses tested)

ALB14-N-100 100 mg
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Protein A-Agarose

6526-1
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Protein A-Agarose

6526-100
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Protein A-Agarose

6526-1000 Ask for price

Protein A-Agarose

6526-25
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Protein A-Agarose

6526-5
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Nickel Agarose Extrachel

6RREXCH-100 100 ml
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Nickel Agarose Extrachel

6RREXCH-25 25 ml
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Nickel Agarose Extrachel

6RREXCH-500 500 ml
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A0222-020 200g
EUR 300

HiQTM Standard Agarose

A0222-050 500g
EUR 537.6

Glutathione Agarose Resin

4B-GLU-10 10 ml
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4B-GLU-100 100 ml
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Biotin Agarose Resin

4BCL-BI-10 10 ml
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Biotin Agarose Resin

4BCL-BI-5 5 ml
EUR 282

GelRed Agarose LE

41029-50G 50G
EUR 384
Description: Minimum order quantity: 1 unit of 50G

GelRed Agarose LE

41029-5G 5G
EUR 124.8
Description: Minimum order quantity: 1 unit of 5G

GelGreen Agarose LE

41030-50G 50G
EUR 384
Description: Minimum order quantity: 1 unit of 50G

GelGreen Agarose LE

41030-5G 5G
EUR 124.8
Description: Minimum order quantity: 1 unit of 5G

Agarose GPG/LE

A2500-100000 100 g
EUR 170.4
Description: Agar is a galactan polysaccharides which extracted from the intracellular matrix in marine algae Rhodophyta. Agarose is a neutral polymer component of agar. Agarose solution transforms into gel after heating. Gel is formed resulting from double helical formation from molecular chains.

Agarose GPG/LE

A2500-500000 500 g
EUR 560.4
Description: Agar is a galactan polysaccharides which extracted from the intracellular matrix in marine algae Rhodophyta. Agarose is a neutral polymer component of agar. Agarose solution transforms into gel after heating. Gel is formed resulting from double helical formation from molecular chains.

Agarose GPG/ME

A2502-100000 100 g
EUR 226.8
Description: analytical and preparative electrophoresis of DNA >1000bpnorthern/southern blottingserum protein electrophoresis.

Agarose GPG/ME

A2502-500000 500 g
EUR 811.2
Description: analytical and preparative electrophoresis of DNA >1000bpnorthern/southern blottingserum protein electrophoresis.

Agarose, Resolute GPG

A2503-100000 100 g
EUR 477.6
Description: resolve differences in bp length by as little as 2%finely resolve DNA fragments from 20-1000bp, rivals polyacrylamidegels are extremely clear and easy to handle due to high gel strengthno detectable inhibition of DNA ligase or the following restriction enzymes:BamH I, Hind II, EcoR I..

Benchmark Agarose LE

A1700 1 PC
EUR 385.98

Benchmark Agarose LE

A1701 1 PC
EUR 120.11

Benchmark Agarose LE

A1705 1 PC
EUR 180.4

Benchmark Agarose HR

A1801-HR 1 PC
EUR 165.08

Benchmark Agarose LM

A1801-LM 1 PC
EUR 311.86

Agarose Ultra Pure

BA01101 100g
EUR 147.6
Description: Ultrapure agarose for separation and further analysis of PCR products.

Agarose Ultra Pure

BA01102 500g
EUR 399.6
Description: Ultrapure agarose for separation and further analysis of PCR products.

ClearSight Agarose Tablets

BA50202 100pcs
EUR 165.6
Description: Ultrapure agarose for separation and further analysis of PCR products.

V5 agarose beads

AE029-100ul 100 ul Ask for price

V5 agarose beads

AE029-200ul 200 ul
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V5 agarose beads

AE029-20ul 20 ul Ask for price

V5 agarose beads

AE029-50ul 50 ul Ask for price

LC3A Agarose, CF

PR15104CF 500 ul
EUR 403.2

RanBP1 Agarose Beads

STA-421 400 µg
EUR 686.4
Description: RanBP1 Agarose Beads selectively pull down the active form of Ran. Beads are colored to allow for a visual check. These are the same beads supplied with our Small GTPase Activation Assays. 400 µg.

Agarose IEF 10g

17046801 EACH
EUR 224.58

Chicken egg ovalbumin protein (OVA, >98% pure, Low endotoxin, antigen grade)

OVA17-N-10 10 mg
EUR 270

Chicken egg ovalbumin protein (OVA, >98% pure, Low endotoxin, antigen grade)

OVA17-N-100 100 mg
EUR 826.8

FD Thionin Solution™ (regular strength)

PS101-1 500 ml
EUR 206.4

FD Hematoxylin Solution™ (regular strength)

PS104-1 500 ml
EUR 240

Hyaluronidase Grade I (Molecular Biology Grade)

CE174 1 g
EUR 232.8

Hyaluronidase Grade I (Molecular Biology Grade)

CE175 5 g
EUR 920.4

Pepsin (>10,000 U/g), Porcine (low endotoxin, salmonella, and bacteria; industrial grade)

PEP16-100 100 g
EUR 242.4

Pepsin (>10,000 U/g), Porcine (low endotoxin, salmonella, and bacteria; industrial grade)

PEP16-1000 1 kg
EUR 1119.6

KT3 antibody (Agarose Immobilized)

60R-KG002AS 200 ul
EUR 548.4
Description: Goat polyclonal KT3 antibody (Agarose Immobilized)

Nickel NTA Agarose Resin

6BCL-NTANi-100 100 ml
EUR 781.2

Nickel NTA Agarose Resin

6BCL-NTANi-25 25 ml
EUR 260.4

Nickel NTA Agarose Resin

6BCL-NTANi-500 500 ml
EUR 3100.8

Protein A-Agarose Resin

55000 1 mL
EUR 158.4

Protein A-Agarose Resin

55005 5 mL
EUR 367.2

Agarose 3:1, 100g

A0226-010 100g
EUR 578.4

Sepro Agarose LE Tablet

A0250-025 25 Tabs (12.5g)
EUR 123.6

Sepro Agarose LE Tablet

A0250-050 500 Tabs (250g)
EUR 465.6

AGAROSE 25G-125G -500G

A01-118-10kg 10 kg Ask for price

AGAROSE 25G-125G -500G

A01-118-2kg 2kg Ask for price

AGAROSE 25G-125G -500G

A01-118-500g 500 g
EUR 592.8

Protein L Agarose Resin

4BCLPL-10 10 ml
EUR 471.6

Protein L Agarose Resin

4BCLPL-2 2 ml
EUR 236.4

Protein L Agarose Resin

4BCLPL-5 5 ml
EUR 340.8

Agarose for DNA electrophoresis

16-0027-500 500 g
EUR 410.4

Rabbit IgG-Agarose conjugate

20009-AS-1 0.5 ml
EUR 196.8

nAb Agarose Control 0.5ml

ABP-NAB-ACNTRL5 500 µl Ask for price

GFP-nAb Agarose 0.25ml

ABP-NAB-GFPA025 250 µl Ask for price

GFP-nAb Agarose 0.5ml

ABP-NAB-GFPA050 500 µl Ask for price

GFP-nAb Agarose 1ml

ABP-NAB-GFPA100 1 ml Ask for price

mNeonGreen-nAb Agarose 0.25ml

ABP-NAB-MNGA025 250 µl Ask for price

mNeonGreen-nAb Agarose 0.5ml

ABP-NAB-MNGA050 500 µl Ask for price

mNeonGreen-nAb Agarose 1.0ml

ABP-NAB-MNGA100 1.0 ml Ask for price

mTFP-nAb Agarose 0.25ml

ABP-NAB-MTFPA025 25 µg Ask for price

mTFP-nAb Agarose 0.5ml

ABP-NAB-MTFPA050 500 µl Ask for price

mTFP-nAb Agarose 1ml

ABP-NAB-MTFPA100 1 ml Ask for price

RFP-nAb Agarose 0.25ml

ABP-NAB-RFPA025 250 µl Ask for price

RFP-nAb Agarose 0.5ml

ABP-NAB-RFPA050 500 µl Ask for price

RFP-nAb Agarose 1ml

ABP-NAB-RFPA100 1 ml Ask for price

Benchmark Agarose 3:1

A1801-31 1 PC
EUR 343.18

Protein A Agarose Resin

BSP095-7 1ml
EUR 112.2

Protein A Agarose Resin

BSP095-8 5ml
EUR 294.9

Glutathione-Agarose (Aff matrix)

GSSH15-AS 1 ml
EUR 343.2

Protein A Agarose Resin

PA09-100 100 ml
EUR 2512.8

Protein A Agarose Resin

PA09-25 25 ml
EUR 1110

Protein A Agarose Resin

PA09-5 5 ml
EUR 349.2

Protein G Agarose Resin

SF022-PG 5ml
EUR 930

PAK1 PBD Agarose Beads

STA-411 400 ?g
EUR 686.4
Description: PAK1 PBD Agarose Beads selectively pull down the active form of Rac and Cdc42. Beads are colored to allow for a visual check. These are the same beads supplied with our Small GTPase Activation Assays. 400 µg.

Rhotekin RBD Agarose Beads

STA-412 400 ?g
EUR 686.4
Description: Rhotekin RBD Agarose Beads selectively pull down the active form of Rho. Beads are colored to allow for a visual check. These are the same beads supplied with our Small GTPase Activation Assays. 400 µg.

RalGDS RBD Agarose Beads

STA-418 400 µg
EUR 686.4
Description: RalGDS RBD Agarose Beads selectively pull down the active form of Rap. Beads are colored to allow for a visual check. These are the same beads supplied with our Small GTPase Activation Assays. 400 µg.

GGA3 PBD Agarose Beads

STA-419 400 µg
EUR 686.4
Description: GGA3 PBD Agarose Beads selectively pull down the active form of Arf. Beads are colored to allow for a visual check. These are the same beads supplied with our Small GTPase Activation Assays. 400 µg.

RalBP1 PBD Agarose Beads

STA-420 400 µg
EUR 686.4
Description: RalBP1 RBD Agarose Beads selectively pull down the active form of Ral. Beads are colored to allow for a visual check. These are the same beads supplied with our Small GTPase Activation Assays. 400 µg.

Streptavidin 6HC Agarose Resin

STV6HC-10 10 ml
EUR 478.8

Streptavidin 6HC Agarose Resin

STV6HC-20 20 ml
EUR 822

Streptavidin 6HC Agarose Resin

STV6HC-5 5 ml
EUR 284.4

Agarose MS PCR Screening

AXY1008 PK10
EUR 5567.76

Agarose LM 50 g

DD777025 EACH
EUR 296.4

FD Cresyl Violet Solution™ (regular strength)

PS102-1 500 ml
EUR 223.2

FD Eosin Y Solution™ (regular strength)

PS103-1 500 ml
EUR 182.4

FD Methyl Green Solution™ (regular strength)

PS105-1 500 ml
EUR 216

FD Neutral Red Solution™ (regular strength)

PS106-1 500 ml
EUR 219.6

FD Azure II Solution™ (regular strength)

PS107-1 500 ml Ask for price

Transport Swab Liquid Amies Regular Flocked Swab

480CE PK50
EUR 150.48

Bovine serum albumin (BSA) protein (>99%, Protease & IgG-free; Low endotoxin; Diagnostic grade)

BSA17-N-100 100 mg
EUR 343.2

Bovine serum albumin (BSA) protein (>99%, Protease & IgG-free; Low endotoxin; Diagnostic grade)

BSA17-N-100G 100 g
EUR 1000.8

Bovine serum albumin (BSA) protein (>99%, Protease & IgG-free; Low endotoxin; Diagnostic grade)

BSA17-N-10G 10 g
EUR 562.8

Bovine serum albumin (BSA) protein (>99%, Protease & IgG-free; Low endotoxin; Diagnostic grade)

BSA17-N-1G 1 g
EUR 634.8

Hi-Bind? Protein G-Agarose

6513-1
EUR 280.8

Hi-Bind? Protein G-Agarose

6513-100
EUR 5468.4

Hi-Bind? Protein G-Agarose

6513-1000 Ask for price

Hi-Bind? Protein G-Agarose

6513-25
EUR 2114.4

Hi-Bind? Protein G-Agarose

6513-5
EUR 679.2

Hi-Bind? Protein A-Agarose

6520-1
EUR 196.8

Hi-Bind? Protein A-Agarose

6520-100
EUR 4105.2

Hi-Bind? Protein A-Agarose

6520-1000 Ask for price

Hi-Bind? Protein A-Agarose

6520-25
EUR 1886.4

Hi-Bind? Protein A-Agarose

6520-5
EUR 594

Hi-Bind? Protein A-Agarose

6520-500
EUR 11739.6

Agarose Standard 50bp - 50.000 bp

604-001 100g
EUR 91.2

Agarose Standard 50bp - 50.000 bp

604-005 1x500g
EUR 222

Agarose Standard 50bp - 50.000 bp

604-005-10 10x500g
EUR 1594.8

Agarose Standard 50bp - 50.000 bp

604-005-2 2x500g
EUR 406.8

Agarose Standard 50bp - 50.000 bp

604-005-5 5x500g
EUR 886.8

AE-6111 Agarose EP Kit

2322178 1unit
EUR 1035.6
Description: 1 el ect r ophor esi s chamber i ncl udi ng. safet y l i dwi t h power l eads, a 12 x 16 cm gel t r ay wi t h 2 dams, 1 comb hol der and 1 comb for 1 mm, 26 &

Piperine, an alkaloid of black pepper seeds can successfully inhibit the antiviral enzymes of Dengue and Ebola viruses, an in silico molecular docking examine

Ebola and Dengue are the important illnesses attributable to RNA viruses, particularly within the tropical components of the globe, together with Asia and Africa, and no outstanding therapeutic choices can be found to this point. Right here, an effort was made to judge the efficacy of black pepper (Piper nigrum L.) alkaloid Piperine as a possible drug by means of computational docking simulation.

Eight structurally important proteins of Dengue and Ebola virus have been chosen as in silico docking targets for Piperine. Absorption, Distribution, Metabolism, and Excretion profile confirmed that Piperine was protected and possessed vital drug-like properties.

Molecular dynamic simulation and binding free power calculation confirmed that Piperine might inhibit Methyltransferase (PDB id 1L9K) of Dengue and VP35 Interferon Inhibitory Area (PDB id 3FKE) of Ebola virus as compared with the industrial antiviral Ribavirin. Moreover, statistical evaluation primarily based on multivariate and clustering approaches revealed that Piperine had extra affinity in direction of viral proteins than that of Ribavirin.

Molecular dynamics research on the impact of floor roughness and floor rigidity on the thermodynamics and dynamics of hydronium ion switch throughout the liquid/liquid interface

Molecular dynamics simulations are used to look at the impact of floor roughness and floor rigidity on the switch of the classical hydronium ion (H3O+) throughout the water/1,2-dichloroethane interface. Free power of switch, hydration construction and dynamics as a operate of the ion location alongside the interface regular are calculated with 6 totally different values of a management parameter whose variation modifies the floor rigidity with out impacting the majority properties of the 2 solvents.

Switch of the classical hydronium ion throughout the water/1,2-dichloroethan interface includes the co-transfer of three hydration shell water molecules impartial of the floor rigidity. Nevertheless, because the interplay between the 2 liquids weakens, rise in interfacial rigidity and reduce in intrinsic water fingering and capillary fluctuations ends in fewer water molecules co-transported with the ion within the second shell and a discount within the size of the finger that the ion is connected to, in line with the diminished measurement of the second hydration shell. First shell water residence time and lateral ion diffusion constants varies with the floor rigidity in a manner which are in line with the above structural perception

Triplet Exciton Transfers and Triplet-Triplet Annihilation in Anthracene Derivatives through Direct versus Superexchange Pathways Ruled by Molecular Packing

Triplet exciton switch (TET) and triplet-triplet annihilations (TTA) in anthracene derivatives, specifically considered one of polymorphs of 9,10-bis(triisopropylsilylethynyl)anthracene (TIPS-ANTp) and 1,2,3,4-tetrafluoro-5,8-bis(trimethylsilylethynyl)anthracene (F4-TMS-ANT), are analyzed theoretically. The digital couplings for TET and TTA are evaluated by way of the diabatization scheme at the side of the time-dependent density useful principle and the multi-reference second-order Møller-Plesset technique.

The TET charge is estimated primarily based on the Fermi’s golden rule contemplating the Franck-Condon issue of intramolecular modes. TTA is analyzed by way of quantum dynamics calculations with the multi-configuration time-dependent Hartree technique. TET within the cofacially stacked F4-TMS-ANT is quicker than that of the slip-stacked TIPS-ANTp. Within the anthracene derivatives, a singlet exciton is decrease in power than a pair of triplets.

F4-TMS-ANT can exhibit an ultrafast TTA through the superexchange pathway mediated by higher-lying cost switch (CT) states, owing to sturdy digital couplings. In distinction, TIPS-ANTp reveals an inefficient TTA through the direct pathway with a small two-electron coupling. The cofacial stacking decreases the power hole to the intermediate CT states, thereby facilitating TET and TTA through the superexchange pathway.

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